09003D04 - 01

	According to 2001/58/EC
	MATERIAL SAFETY DATA SHEET
	Catalogue N° : 09003D04 Printing date : 20/05/2007

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
1.1. Identification of the substance or preparation
FR 5

1.2. Use of the substance/preparation Washing fluid for pre-press stages 1.3. Company/undertaking identification FUJIFILM Europe NV EUROPARK-NOORD 21-22 B-9100 SINT NIKLAAS TEL : +32 (3)760 02 00 FAX : +32 (3)776 91 22 1.4. Emergency telephone +32 (0)3 760 02 00
2. COMPOSITION / INFORMATION ON INGREDIENTS
Components contributing to hazard:

w/w%	CAS N°	EINECS N°	`Chemical Name Symb.R-phrases`
30-50 . 15-30 . 10-20 . 10-20 . 1-5 . 1-5 . 1-5 . 0,5-1,5 . 0,5-1,5 .	111-65-9 . 64742-49-0 . 31394-54-4 . 108-87-2 . 1330-20-7 . 123-86-4 . 110-82-7 . 110-54-3 . . .	203-892-1 . 265-151-9 . 250-610-8 . 203-624-3 . 215-535-7 . 204-658-1 . 203-806-2 . 203-777-6 . . .	OCTAN FXnN R:11-38-50/53-65-67 NAPHTA, HYDROTREATED LIGHT FXNN R:11-38-51/53-65-67 HEPTANE & ISOMERS FXnN R:11-38-50/53-65-67 METHYLCYCLOHEXANE FXnN R:11-38-51/53-65-67 XYLENE Xn R:10-20/21-38 N-BUTYLACETATE - R:10-66-67 CYCLOHEXANE FXnN R:11-38-50/53-65-67 N-HEXAN FXnN R:11-38-48/20-62-5153-65-67 HEXANE, ISOMERS FXnN R:11-38-51/53-65-67

3. HAZARDS IDENTIFICATION
Most important hazards : Highly flammable. Irritating to skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness.
4. FIRST AID MEASURES
Eye contact Irrigate with flowing water immediately and continuously for 15 minutes. Consult medical personnel. Skin contact Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing Ingestion Consult a physician or transport to emergency facility immediately Inhalation Remove to fresh air. Consult a physician. Further information None
5. FIRE-FIGHTING MEASURES
5.1. Suitable extinguishing media: Water fog, carbon dioxide, foam, dry chemicals. 5.2. Extinguishing media to avoid: Water jet. 5.3. Further information: Keep containers cool by spraying with water.
6. ACCIDENTAL RELEASE MEASURES
- Wear adequate personal protective equipment, see section 8 ( exposure control / personal protection ). - Spills should be contained by and carried with suitable absorbent material and removed from disposal. - Dispose of according to local and national regulations. - Prevent from entering into soil, waterways and groundwater.
7. HANDLING AND STORAGE
7.1. Handling Avoid eye and skin contact. Wash hands and exposed skin before eating, drinking or smoking and after work. Use only in a well ventilated area. Ingestion, exposure to skin and eyes and inhalation of any generated vapours should be avoided. Wear suitable protective clothing, gloves and eye/face protection. Do not consume or store food in the working area. 7.2. Storage Keep containers tightly closed. Store in a well ventilated, cool, dry area. Take measures to prevent electrostatic charging. Explosible with air in a vaporous/gaseous state. Storage class : 3A (VCI storage system), Vbf A I
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Exposure limit values (INGREDIENTS INFORMATION) OCTAN MAK ( Deutschland, TRGS 900 ) = 2350 mg/mł - 500 ml/mł TLV-TWA = NA NAPHTA, HYDROTREATED LIGHT MAK ( Deutschland, TRGS 900 ) = 1000 mg/mł - 200 ppm HEPTANE & ISOMERS MAK ( Deutschland, TRGS 900 ) = 500 ppm - 2000 mg/mł METHYLCYCLOHEXANE TLV-STEL = 400 ppm - 1633 mg/mł XYLENE TLV-TWA = 100 ppm - 434 mg/mł (ACGIH) TLV-STEL = 150 ppm - 651 mg/mł (ACGIH) N-BUTYLACETATE MAK ( Deutschland, TRGS 900 ) = 480 mg/mł CYCLOHEXANE TLV-STEL = 300 ppm - 1045 mg/mł N-HEXAN MAK ( Deutschland, TRGS 900 ) = 180 mg/mł TLV-TWA = NAv HEXANE, ISOMERS MAK ( Deutschland, TRGS 900 ) = 200 ppm - 720 mg/mł 8.2. Exposure controls Respiratory protection: no respiratory protection needed under normal conditions. Good ventilation should be sufficient. Hand protection: use chemical resistant gloves. In case of prolonged immersion or frequently repeated contact use gloves made of the material : nitrile rubber. Eye protection: use chemical safety goggles. Eye wash fountain should be located in immediate work area. Other: appropriate protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid Colour : Orange Odour : Mild Boiling point/range : 98 - 140 °C Melting point/range : < -20 °C Flash point °C : -2 Vapour pressure (20°C) : 11,1 kPa Density (20°C) Kg/L : 0,735 Solubility in water (25°C) : Insoluble Explosive limit lower : 0,7 vol% Explosive limit upper : 7 vol% Viscosity : 0,76 mPas Autoignition temperature : > 200 °C

10. STABILITY AND REACTIVITY
10.1. Conditions to avoid Heating. The product is stable under normal storage conditions. 10.2. Materials to avoid Keep away from oxidising material(s). 10.3. Hazardous decomposition products Formation of CO2 and CO fumes is possible.
11. TOXICOLOGICAL INFORMATION
Acute toxicity (INGREDIENTS INFORMATION) OCTAN LD50 (Oral Rat) = NA LD50 (Dermal rabbit) = NA NAPHTA, HYDROTREATED LIGHT LD50 (Oral Rat) = NAv HEPTANE & ISOMERS LD50 (Oral Rat) = NA METHYLCYCLOHEXANE LD50 (Oral Rat) = NA N-BUTYLACETATE LD50 (Oral Rat) = > 4700 mg/kg LD50 (Dermal rabbit) = > 5000 mg/kg CYCLOHEXANE LD50 (Oral Rat) = NA N-HEXAN LD50 (Oral Rat) = NAv HEXANE, ISOMERS LD50 (Oral Rat) = NA Skin contact Irritating to skin. Further information
12. ECOLOGICAL INFORMATION
12.1. Ecotoxicity OCTAN LC50 (Fish, 96 hours) = NA NAPHTA, HYDROTREATED LIGHT LC50 (Fish, 96 hours) = NAv HEPTANE & ISOMERS LC50 (Fish, 96 hours) = NA METHYLCYCLOHEXANE LC50 (Fish, 96 hours) = NA N-BUTYLACETATE LC50 (Leuciscus idus, orfe, 96h) = 62 mg/l CYCLOHEXANE LC50 (Fish, 96 hours) = NA N-HEXAN LC50 (Fish, 96 hours) = NAv HEXANE, ISOMERS LC50 (Fish, 96 hours) = NA 12.2. Mobility not known 12.3. Persistence and Degradability not known 12.4. Bioaccumulative potential
13. DISPOSAL CONSIDERATIONS
Dispose of according to local and national regulations. Containers must be disposed of in accordance with local regulations. EAK : 07 06 04 Other organic solvents, cleaning agents and mother liquor.
14. TRANSPORT INFORMATION
UN N° : 3295 PSN : HYDROCARBONS, LIQUID, N.O.S. (Isoheptane/n-heptane) ADR/RID Class:3 labels :3 Pack. Group:II Code :D1E TREMcard :3.3295B-201 Spec. Prov.:649 Pack. Inst.:P001,IBC02,R001 Lim. Quant.:LQ4 IMDG Class:3 Subs. Risk :NA Pack. Group:II EmS fire:F-E EmS Storage:S-D IBC. Inst. :IBC02 Pack. Inst.:P001 Lim. Quant.:1L Mar.Poll:N ICAO/IATA Class:3 Subs. Risk :NA Pack. Group:II Passenger and Cargo Aircraft. Pkg Inst:305 Max Net Qty/Pkg:5L Cargo Aircraft Only . Pkg Inst:307 Max Net Qty/Pkg:60L Ltd Qty . Pkg Inst:1L Max Net Qty/Pkg:Y305
15. REGULATORY INFORMATION
EU Classification and User Label Information: Contains : MIXTURE OF HYDROCARBONS, FREE OF AROMATES Symbol(s) : F Xn N R(isk) phrase(s) : R11 : Highly flammable. R38 : Irritating to skin. R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 : Harmful: may cause lung damage if swallowed. R67 : Vapours may cause drowsiness and dizziness. S(afety) phrase(s) : S9 : Keep container in a well-ventilated place. S16 : Keep away from sources of ignition -- No smoking. S23 : Do not breathe vapour. S24 : Avoid contact with skin. S33 : Take precautionary measures against static discharges. S43 : In case of fire, use water fog, carbon dioxide, foam, dry chemicals - Never use water. S57 : Use appropriate container to avoid environmental contamination. S60 : This material and its container must be disposed of as hazardous waste. S62 : If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Other information : Nota P ( 2001/58/EC ) : < 0,1 % Benzene ( CAS 71-43-2, EC 200-753-7 ) Explosible with air in a vaporous/gaseous state. WGK: 2

16. OTHER INFORMATION
The use of the preparation is restricted to professional users| The above mentioned data correspond to our present state of knowledge and experience. The safety data sheet serves as description of the products in regard to necessary safety measures. The indications have not the meaning of guarantees on properties. --------------------------------------------------------------------------- Date of issue: 01.10.2005 Supersedes edition of: 01.04.2004 --------------------------------------------------------------------------- NAv : Not available NA : Not applicable RISK PHRASES MENTIONED IN PARAGRAPH 2: R10 : Flammable. R11 : Highly flammable. R20/21 : Harmful by inhalation and in contact with skin. R38 : Irritating to skin. R48/20 : Harmful: danger of serious damage to health by prolonged exposure through inhalation. R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R5153 : R62 : Possible risk of impaired fertility. R65 : Harmful: may cause lung damage if swallowed. R66 : Repeated exposure may cause skin dryness or cracking. R67 : Vapours may cause drowsiness and dizziness.